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9 - 9 . El proceso Deacon para producir cloro se basa en la reacci n catal tica de fase gaseosa H C l +

9-9. El proceso Deacon para producir cloro se basa en la reaccin cataltica de fase gaseosa
HCl+14O212Cl2+12H2O
Furusaki ?36 estudi la cintica de esta reaccin reversible, con un catalizador de CuCl2,KCl,
SnCl2 sobre sllice en diferentes reactores diferenciales e integrales. La velocidad de desapari-
cin del HCl se correlaciona por medio de la ecuacin:
(a) Describa una serie de etapas fundamentales de adsorcin y reaccin superficial que pro-
duzca esta expresin de velocidad.
(b) Los datos de velocidad a 350C, obtenidos en el reactor diferencial con una alimentacin
de HCl y aire (sinCl2O2O) son como sigue:
450 Ingeniera de la cintica qumica
Con base en estos datos, evale tantas constantes k,K1 y K2 como le sea posible.
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