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A + B + C Y (note the reaction is not balanced) Trial [A] (mol/L) [B] (mol/L) [C] (mol/L) Rate (molL-1s-1) 1 0.0020 0.0020 0.0040

A + B + C Y (note the reaction is not balanced)

Trial

[A] (mol/L)

[B] (mol/L)

[C] (mol/L)

Rate (molL-1s-1)

1

0.0020

0.0020

0.0040

4.48x10-6

2

0.0020

0.0040

0.0040

4.48 x10-6

3

0.0020

0.0060

0.0040

4.48 x10-6

4

0.0020

0.0080

0.0040

4.48 x10-6

5

0.0040

0.0080

0.0040

1.79 x10-5

6

0.0060

0.0080

0.0040

4.03 x10-5

7

0.0060

0.0080

0.0010

1.01 x10-5

8

0.0060

0.0080

0.0020

2.02 x10-5

9

0.0060

0.0080

0.0030

3.02 x10-5

Rate = k[A]2[B]0[C]1

. What will most likely happen to the rate constant k if the temperature of the reaction was increased by 10oC?

6. A chemist proposed a mechanism for this reaction.

Step 1: 2A + C A2C (slow)

Step 2: A2C + B F (fast)

Step 3: F + C Y___________(very fast)

Net:

a) Cancel terms and write the overall (net) reaction.

b) Is this reaction mechanism supported by the empirical evidence? Why or why not.

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