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A binary system exhibits 2 liquid phases at a certain pressure, with compositions x 1 = 0 . 2 and x 1 = 0 .

A binary system exhibits 2 liquid phases at a certain pressure, with compositions x1=
0.2 and x1=0.9. The vapor pressures are P1 sat =2 atm; P2 sat =7atm.
a) Estimate the activity coefficients 1 and 2. Explain any assumptions.
b) Evaluate the 3-phase pressure and all the mole fractions (in the liquids and
Vapor phase) at the three-phase pressure.
c) Sketch the P-x1-y1 diagram.
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