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A feed stream containing 7 0 mole % acetaldehyde ( C 2 H 4 O ) and the balance oxygen enters a reactor. The following

A feed stream containing 70 mole% acetaldehyde (C2H4O) and the balance oxygen
enters a reactor. The following reactions occur inside the reactor:
Reaction 1: C2H4O+(12)O2=>C2H4O2
Reaction 2: C2H4O+(52)O2=>2CO2+2H2O
Produces desired product (acetic acid)
Side reaction for combustion of acetaldehyde
Acetic acid (C2H4O2) is the desired product. A separation process following the reactor generates
three product streams: one stream containing 84% of the unreacted acetaldehyde is recycled
back to the reactor; the second contains the remaining acetaldehyde and CO2; and the third
contains acetic acid and water. Assume a basis of 100molh fed to the reactor.
a.(4 pts) Identify the overall system and all of the subsystems on the given flowchart above by
drawing a dashed outline around each. You can redraw the diagram exactly as shown above
on your own paper or copy and paste the above diagram.
b.(15 pts) Perform the DOF analysis for the overall system and each of the identified
subsystems. Rules:
(i) Use the extent of reaction DOF approach for reactive systems.
(ii) Specify the unknown variables and type of equations used when doing DOF analysis.
(iii) Treat every DOF analysis separate from the other systems.
(iv) Do not assume or carry over "known" variables from previous systems with 0DOF.
(v) DO NOT write the complete equations in the DOF.
C.(16 pts) Write the equations you would use to calculate n3,i4,i5, the fractional yield of
acetic acid in the reactor (hint: think of which species this expression needs to be written in
terms of), and the selectivity of acetic acid to carbon dioxide production in the reactor.
Use extent of reaction balances for any reactive species. Label each equation using words
(e.g., extent of reaction for O2). De not perform anycalculations.
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