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A first - order, heterogeneous, irreversible reaction is taking place within a catalyst pore which is plated with platinum entirely along the length of the

A first-order, heterogeneous, irreversible reaction
is taking place within a catalyst pore which is plated with platinum entirely along the length of
the pore. The reactant concentration at the plane of symmetry (i.e., equal distance from the pore
mouths) of the pore is equal to one-tenth the concentration at the pore mouth. The
concentration at the pore mouth is 0.001 mol/L, the pore length (2L) is 2 x 103 cm, and the
diffusion coefficient is 0.1 cm 2
/s.
Write a differential molar balance for the pore, assuming
that you have no gradients of concentration in the radial
or angular directions. State the boundary conditions.
What
is the expression for the Thiele modulus,
, in this case?
HINT: For part (a) assume that the reaction is happening in the bulk of the pore. For part (b),
write the differential equation you obtained in part (a) in terms of the dimensionless parameters
(C A /C AS) and
(z/L). The term multiplying the dimensionless concentration y will be equal to the
Thiele modulus squared.

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