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( a ) For the solidification of iron, calculate the critical radius r * * and the activation free energy G * * if nucleation
a For the solidification of iron, calculate the critical radius and the activation free energy if nucleation is homogeneous. Values for the latent heat of fusion and surface free energy are and respectively. Use the supercooling value and the melting point of iron is
Critical Radius, nm
Activation Free Energy J
b Now calculate the number of atoms found in a nucleus of critical size. Assume a lattice parameter of for solid iron at its melting temperature.
ns for Critical Size atomscritical nucle
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