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A gas that contains C O 2 is contacted with liquid water in an agitated batch absorber . Henry's law gives the equilibrium solubility of

A gas that contains CO2 is contacted with liquid water in an agitated batch absorber. Henry's law gives the equilibrium solubility of CO2 in water, CA=pAhA, where CA(molL) is the CO2 concentration in solution, pA(atm) is the partial pressure of CO2 in the gas phase and hA is Henry's law constant. The rate of transfer of CO2 from the gas to the liquid per unit area of gas-liquid interface is given by raa(molcm2(s))=k(C**-CA) where C**A is the concentration of CO2 that would be in equilibrium with the CO2 in the gas phase (:pAhA}. Suppose the gas-phase total pressure is P(atm) and contains yA mol fraction of CO2, and the liquid phase initially has V(cm3) of pure water with the agitation of the liquid phase sufficient to neglect spatial composition dependency, and if the amount of absorbed CO2 is low enough for P,V, and yA to be assumed constant. Write a differential balance on CO2 in the liquid phase and solve the differential equation to show that CA(t)=C**A[1-exp(kStV)].
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