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A magnesium alloy with 5 w t % aluminum is continuously solidified, for example in a zone refining furnace. Temperature and composition in the liquid
A magnesium alloy with aluminum is continuously solidified, for example in a
zone refining furnace. Temperature and composition in the liquid and growing solid
follow the red trace below on the phase diagram.
a Sketch the concentration profile from the solid across the interface into the liquid
phase.
b In the frame of reference of the moving interface, write the equation for aluminum
concentration in the liquid phase, assuming the liquid is quiescent no turbulence
etc. and aluminum diffusivity is uniform.
c If solidification rate is limited by aluminum diffusion away from the interface in
the liquid phase, is this interface stable or unstable? Briefly explain.
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