Question: A raindrop is formed in a cloud and comes to equilibrium with Poco2 =104.5 bar. The water droplet then passes over a smoke stakes

A raindrop is formed in a cloud and comes to equilibrium with

A raindrop is formed in a cloud and comes to equilibrium with Poco2 =104.5 bar. The water droplet then passes over a smoke stakes and absorbs 103 M H2SO4. (Note that for H2CO3 , pKa1= 6.35, pka2= 10.33, Hco2= 28.8 bar.L.mol1) a. Draw a log C-pH diagram for the system and find the pH and alkalinity. (Show the species, reactions, mass action laws, mass balances, charge balance and proton condition) b. The droplet next passes over feedlot and comes to equilibrium with PNH3=10-92 bar. The droplet remains in equilibrium with atmospheric CO2 as it equilibrates with the NH3. Modify the graph to include NH3 and find the pH, Alkalinity. (Note that for NH3=9.25 , HNH3=0.017bar.L.mol1)

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