A sediment porewater at pH 8.0 is in equilibrium with ZnS(s) and contains 10-1 M total dissolved sulfide and 10-4 M dissolved inorganic carbon. (a) Determine the total dissolved zinc in this system, in mg/L. Assume that ZnCO3(s) does not form in the system. Use pKa1 = 7.0 and pKa2 = 13.9 for the sulfide system. (b) Calculate the saturation index for ZnCO3(s). Does the saturation index confirm that ZnCO3(s) will not form? Explain