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A sharp separation of benzene ( B ) and cyclohexane ( C H ) by distillation is impossible because of an azeotrope at 7 7

A sharp separation of benzene (B) and cyclohexane (CH) by distillation is impossible because of
an azeotrope at 77.6C, as shown by the data of K.C. Chao [PhD thesis, University of Wisconsin
(1956)]. At 1 atm:
(a) Use the data to calculate and plot the relative volatility of benzene with respect to
cyclohexane versus benzene composition in the liquid phase. What happens in the vicinity of the
azeotrope?
(b) Estimate the composition of the azeotrope. Is it a maximum boiling or minimum-boiling
azeotrope?
(c) Using a process simulator with the Wilson equation to compute and plot the activity
coefficients. How well do they compare with the experimental data?
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