Question
A small laboratory fixed bed 10.16 cm in diameter and 16 cm in length containing 600 g of activated carbon (C), has been used to
A small laboratory fixed bed 10.16 cm in diameter and 16 cm in length containing 600 g of activated carbon (C), has been used to adsorb n-butanol (B) from air containing 365 ppm of B. Measurements of the effluent concentration in terms of cout/cF as a function of time t are:
Cout/cF | 0.0019 | 0.003 | 0.008 | 0.18 | 0.04 | 0.07 | 0.15 | 0.24 | 0.66 | 0.81 | 0.94 | 1.00 |
t, hr | 5 | 5.5 | 6 | 6.5 | 7 | 7.5 | 8 | 8.5 | 10 | 11 | 12 | 13 |
Other pertinent data are: entering superficial gas velocity, us = 58 cm/s; T = 25C; P = 737 mm Hg; bed porosity, =0.456; average particle diameter, dp = 0.37cm; and butanol MW = 74.12 g/mol. A cylindrical vessel with an inside diameter of 2 ft and a height of 5 ft is available to conduct the adsorption on an industrial scale. The vessel can be packed with carbon to a 4 ft height. Plot the laboratory data and determine: (a) the mass velocity of the gas as it enters the bed in g gas/cm2 h, (b) the equilibrium loading of the carbon laboratory bed in g B/g C, and (c) the fraction of the laboratory bed utilied in the experiment if the breakthough time is taken at cout/cF = 0.05. For the industrial application calculate (d) the gas flow rate in kg/h for the same entering superficial velocity used in the laboratory experiment, (e) the fraction of the industrial bed that can be utilized, and (f) the estimated breakthrough time in h.
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