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A(1)/B(2) ikili bir karma ait ayrk (excess) Gibbs serbest enerjisi Margules denklemi ile aadaki ekilde ifade edilebilmektedir: GE = = (1.40 x + 0.60

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A(1)/B(2) ikili bir karma ait ayrk (excess) Gibbs serbest enerjisi Margules denklemi ile aadaki ekilde ifade edilebilmektedir: GE = = (1.40 x + 0.60 x2 )x1x2 Bileenlerin 50C'deki buhar basnlar: Psat = 80 kPa ; Pat = 35 kPa a) Buhar fazn ideal gaz davranm gstermekte olduunu esas alarak, 50C'de denge halinde bulunan buhar sv fazlar iin sv fazn 0.25, 0.50 ve 0.75 mol fraksiyonlarna sahip olmas durumundaki habbe noktas basnlarn (bubble pressures) ve buhar fazn bileimlerini hesaplaynz. b) Gaz fazn ideal davranmayp, kinci Virial Katsay esasl virial hal denklemi ile ifade edilebildiini varsayarak, ksm a)'da istenilen zellikleri x1=0.25 durumu iin hesaplaynz, sonular yorumlaynz. VER : B11 = -950 cm/mol ; B22 = -1500 cm/mol ; B12 = 50 cm/mol

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