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Account for the following: (a) Aniline cannot be prepared by the ammonolysis of chlorobenzene under normal conditions. (b) N-ethylethanamine boils at 329.3K and butanamine boils

Account for the following:
(a) Aniline cannot be prepared by the ammonolysis of chlorobenzene under normal conditions.
(b) N-ethylethanamine boils at 329.3K and butanamine boils at 350.8K, although both are isomeric in nature.
(c) Acylation of aniline is carried out in the presence of pyridine.

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