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AHvap Consider the gas-phase reaction: A +B=C Product C has a fairly low vapor pressure, so we are concerned about the formation of a liquid
AHvap Consider the gas-phase reaction: A +B=C Product C has a fairly low vapor pressure, so we are concerned about the formation of a liquid phase in the reactor. The Clausius-Clapeyron equation well represents the vapor pressure of component C as a function of temperature InPc = c - RT The reactor is initially filled with an equimolar mixture of A and B. The equilibrium constant at T=298K is K=8, the reaction is exothermic with AH -10 kcal/mol, and the system pressure is P=1.0atm. Components A and B are not very soluble in liquid C. The heat of vaporization of component C is AHvap 5 kcal/mol, and the value of the Clausius-Clapeyron constant is c = 7.53. a) Over what temperature range does the reactor contain a liquid phase? b) If the reaction is endothermic with AH = 10 kcal/mol, over what temperature range does the reactor contain a liquid phase? =
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