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Although the Schrodinger equation for helium itself cannot be solved exactly there exist helim-like systems that do admit exact solutions. A simple example is a
Although the Schrodinger equation for helium itself cannot be solved exactly there exist helim-like systems that do admit exact solutions. A simple example is a rubber-band helium, in which the Coulomb forces are replaced by Hookes law forces:
H = -2/(2m)(12 +22) + mw2(r12 +r22) lmw2|r1 + r2|2
(a) show that the change of variables from r1, r2 to
u = (1/2)(r1 + r2) v = (1/2)(r1 - r2)
turns the Hamiltonian into two independent three-dimensional harmonic oscillators.
(b) What is the exact ground state energy for this system? (6 pts)
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