Question
An FCC metal possesses nitrogen (N) interstitial species. In this metal, the N has an associated diffusion coefficient of 2.5610 7 cm 2 /s at
An FCC metal possesses nitrogen (N) interstitial species. In this metal, the N has an associated diffusion coefficient of 2.56107 cm2/s at 600 C. Assume the lattice parameter of this FCC metal is 0.50 nm (5 108 cm).
A.) Assume that the nitrogen diffuses between FCC octahedral sites in this crystal. Determine the jump distance NN (where NN stands for nearest neighbor) in this system. At 600 C, what fraction of attempted jumps are successful? Remember that the lattice vibration frequency is = 1013s 1 .
B.) In this system, the diffusion coefficient is 1.12 1010cm2/s at 300 C. Find both the activation energy and the pre-exponential factor for this interstitial diffusion process.
C.) Calculate the random walk displacement and total distance traveled by an interstitial N in this FCC metal at 600 C in on second.
D.) The equation for the random walk displacement rRandom = (t) seems to suggest that direct diffusion via the next-nearest-neighbor (NNN) octahedral site (positioned at a distance of a), would increase the mean random walk displacement by a factor of a/NN. Does this make sense? If so, why? If not, how can you reconcile this odd apparent behavior - that random walk jumps between next-nearest neighbors would yield larger random walk displacements than jumps between nearest neighbors?
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