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Answer ALL parts Molecule x , molecule Y and molecule Z have the related structures shown below: Spectra for each of the molecules have been
Answer ALL parts
Molecule molecule and molecule have the related structures shown below:
Spectra for each of the molecules have been recorded and are presented in the accompanying analytical data booklet as three datasets: dataset dataset and dataset Gas phase IR spectra are shown on the left, and electron impact ionization mass spectra on the right.
Molecule has the composition carbon, oxygen and hydrogen.
a Calculate the atom ratio carbon:oxygen:hydrogen in molecule and suggest a complete chemical structure for molecule stating an identity for the group
b Calculate the Index of Hydrogen Deficiency IHD for molecule and explain why it is consistent with the structure you have suggested in part a
c All three molecules give rise to signals in the mass spectra at and For each of the three molecules, identify the structures of the cations responsible for these two signals. Identify the fragmentation pathway responsible for the cation.
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