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Assignment 3 (group A) (6%) Due January 4, 2022 @ 5:00 PM Q1. Determine the Arrhenius parameters (A and Ex) from the following data: (3
Assignment 3 (group A) (6%) Due January 4, 2022 @ 5:00 PM Q1. Determine the Arrhenius parameters (A and Ex) from the following data: (3 marks) T (K) k (5-1) 288 300 350 5.71x10-16 5.68x10-14 4.15x10-9 400 3.06x10-7 450 4.55x10-6 A (units) E. (kJ/mol) Q2. (12 marks) Consider the consecutive unimolecular reaction A -I P with rate constants ka and ko. (a) Plot [A], [1], and [P] versus time using their corresponding expressions in your text. Given [A]. = 0.25 M, ka = 0.2 s?, ko = 0.15-!, t=0, 2, 5, 9, and 15 seconds. Estimate maximum concentration of I (Imas) and time at which I will be presentat greatest concentration (tmax). (b) Repeat the calculation but with ko = 0.8 5-1 No need to estimate [I]max and tmar in this part
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