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BET isotherm deals with multilayer adsorption on a substrate, shown as below equation: ! = & ' . . . ( 6 ) Where z

BET isotherm deals with multilayer adsorption on a substrate, shown as below equation: !=&'...(6)Where z p/p*, p* is the vapour pressure above a layer of adsorbate that is more than one molecule thick and which resembles a pure bulk liquid. Vmon is the volume corresponding to monolayer coverage, and c is a constant which is large when the entalphy of desorption from a monolayer is large compared with the entalphy of vaporization of liquid adsorbate. The data in Table Q4(b) relate to the adsorption of N2 on rutile (TiO2) at 75 K. Confirm that it fit a BET isotherm in the rage of pressure reported, and determine the value of Vmon and c.MATR 2313 Thermodynamics of Materials(15)b)!()*'){)*()*&)'}"#$p/torr 1.20 V/mm3601Table Q4(b) : Adsorption of N2 on rutile surface14.045.887.5127.7164.4204.7720822935104611461254

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