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Bismuth has a negative slope on the melting (fusion) curve. Using the questions below as a guide, show that bismuth contract upon melting, without
Bismuth has a negative slope on the melting (fusion) curve. Using the questions below as a guide, show that bismuth contract upon melting, without employing the Clausius-Clapeyron equation. (See Finn section 9.7. for a similar example) (a) Sketch the specific Gibbs free energies of both phases as a function of pressure using the p-T phase diagram, (b) Explain how you obtained the sketch of the specific Gibbs free energies. (c) Sketch the specific volumes of both phases as a function of pressure. (d) Explain how you obtained the sketch of the specific volumes, hence show that bismuth contracts upon melting.
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Physics Principles with Applications
Authors: Douglas C. Giancoli
7th edition
978-0321869111, 321625927, 9780321733627, 321869117, 9780321625922, 321733622, 978-0321762429
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