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C 3 H 8 ( l i q . ) C 3 H 6 ( l i q . ) + H 2 ( g

C3H8(liq.)C3H6(liq.)+H2(gas) Desired Reaction (80% Selectivity)
C3H8(liq.)CH2=C=CH2(liq.)+2H2(gas) Undesired Reaction (20% Selectivity)
5CH2=C=CH2(liq.)+5H2(gas)C15H30(solid) Very Fast Polymerization
Because a single-pass propane conversion of only 40% is expected with this catalyst, it is thought that a
recycle/purge dehydrogenation reactor will be able to achieve a much higher overall conversion of
propane to propylene. Experiments have shown that the catalyst can tolerate C4+ species without losing
activity. A plate-and-frame filter press following the reactor will remove virtually all of the suspended
polymerization solids formed in the reactor.
A product recovery distillation column following the press will produce a propylene-rich (95 mole %)
liquid distillate (from top of column) product with a target flow rate of 250MM pounds per calendar
year. The unit will also be designed to recover 97.5% of the propane in the column feed; that is 97.5%
of the propane leaves in the bottom. The column's condenser (which condenses the distillate) will be
refrigerated to produce a vent gas stream containing 95mol%H2 and 5mol% propylene. All of the
hydrogen leaves in the vent. The bottoms liquid (85% of which will be recycled to the reactor inlet) will
contain propane, propylene, and n-butane. This column, as well as the feed fractionation column, will be
equipped with a partial reboiler and valve trays that are 80% efficient. The utilities available at the site
are recirculated process water at 80F, refrigeration ({:COP=3), and saturated steam at 150 psig.
Please assist the investigation of the feasibility of the proposed FCC diversification option by
completing the following task:
Use your diagram to complete a full material balance and create a stream table. Calculate the required
feed rate (MMlbsyr) and calculate the overall % conversion of propane in the surplus NGL refinery
stream.
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