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Calcium carbonate ( C a C O 3 ) has two common crystalline forms, calcite and aragonite, with the following thermodynamic data: calcite: V =

Calcium carbonate (CaCO3) has two common crystalline forms, calcite and aragonite, with
the following thermodynamic data:
calcite: V=36.93cm3,fG=-1128.8kJ
aragonite: V=34.15cm3,fG=-1127.8kJ
(a) Which form is stable at Earth's surface and why?
(b) At room temperature, calculate the pressure at which the other form should become
stable.
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