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Calculate theheat of solution(q rxn ) for each trial. Find q soln first. The heat of the dissolution (q soln ) is calculated using the
- Calculate theheat of solution(qrxn) for each trial. Find qsolnfirst. The heat of the dissolution (qsoln) is calculated using the formula q = -cmT where c is the heat capacity (approximated by the heat capacity of water as 4.184 Jg-1-1), m is the mass of the solution, and T is the temperature change. The heat capacity of the calorimeter will not be included in the calculation.
- Calculate the H for each trial in kJ/mol using the heat of solution (qrxn) and the moles of the solid.
- he molar enthalpy change is just the heat of dissolution over n, the number of moles solid, or H = q / n. Since the temperature decreases, the reaction is endothermic and Ho should be positive.
- Average the Hs for your trials.
- Calculation of Go: Look up the value of Keqfor the solid used (The equilibrium constant, Keq, is simply the number of moles of urea used to make a saturated solution divided by the total volume in L). The free energy change of the dissolution is calculated using the formula Go= -RTlnKeqwhere R is the gas constant (8.31451 J K-1mol-1) and T is the temperature in Kelvin.
The molar mass of urea is 60.06 grams per mol
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