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Calculate theheat of solution(q rxn ) for each trial. Find q soln first. The heat of the dissolution (q soln ) is calculated using the

  1. Calculate theheat of solution(qrxn) for each trial. Find qsolnfirst. The heat of the dissolution (qsoln) is calculated using the formula q = -cmT where c is the heat capacity (approximated by the heat capacity of water as 4.184 Jg-1-1), m is the mass of the solution, and T is the temperature change. The heat capacity of the calorimeter will not be included in the calculation.
  2. Calculate the H for each trial in kJ/mol using the heat of solution (qrxn) and the moles of the solid.
  3. he molar enthalpy change is just the heat of dissolution over n, the number of moles solid, or H = q / n. Since the temperature decreases, the reaction is endothermic and Ho should be positive.
  4. Average the Hs for your trials.
  5. Calculation of Go: Look up the value of Keqfor the solid used (The equilibrium constant, Keq, is simply the number of moles of urea used to make a saturated solution divided by the total volume in L). The free energy change of the dissolution is calculated using the formula Go= -RTlnKeqwhere R is the gas constant (8.31451 J K-1mol-1) and T is the temperature in Kelvin.

The molar mass of urea is 60.06 grams per mol

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