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Catalytic asymmetric epoxidation of indene using the Jacobsen/Katsuki Mn-salen complex shown below, along with m-CPBA and N-methylmorpholine N-oxide (NMO) as oxidant/reoxidant, gave the enantiomer of
Catalytic asymmetric epoxidation of indene using the Jacobsen/Katsuki Mn-salen complex shown below, along with m-CPBA and N-methylmorpholine N-oxide (NMO) as oxidant/reoxidant, gave the enantiomer of indene oxide shown below with high enantioselectivity. The \%ee was shown to be temperature dependent. Using the data in the table above, determine the difference between the enthalpies and entropies of activation (H+and S+)for the formation of the major and minor enantiomers of the indene oxide product. Determine the difference between the Gibbs energies of activation (G) at 20C, and hence determine the % ee that would be obtained in this reaction at this temperature
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