Question
Chapter 14, Problem 14.09 Multistep For a linear polymer molecule, the total chain length L depends on the bond length between chain atoms d, the
Chapter 14, Problem 14.09 Multistep For a linear polymer molecule, the total chain length L depends on the bond length between chain atoms d, the total number of bonds in the molecule N, and the angle between adjacent backbone chain atoms , as follows: L = Nd sin ( ) (14.11) Furthermore, the average end-to-end distance for a series of polymer molecules r in Figure 14.6 is equal to r= =dVN (14.12) A linear poly(vinyl chloride) has a number-average molecular weight of 400000 g/mol; compute average values of L and r for this material. Part 1 x Carefully review Section 14.5 and the mer units in Table 14.3. Did you remember to multiply the number of atoms in the mer by its individual atomic weight? Did you total them correctly? If you are having difficulty with this problem, you may wish to review: Solving Equations Graphing Overview Calculate the repeat unit molecular weight of poly(vinyl chloride) in g/mol. Click here to access Table 14.3. Atomic weights for several elements are included in the following table: Carbon 12.01 g/mol Chlorine 35.45 g/mol Fluorine 19.00 g/mol 1.008 g/mol Hydrogen Oxygen 16.00 g/mol m = g/mol the tolerance is +/-9% SHOW HINT Attempts: 2 of 3 used SAVE FOR LATER SUBMIT ANSWER Part 2 What is the degree of polymerization of this polymer if the number-average molecular weight is 400000 g/mol? DP =
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