Question
Consider a chain-growth polymerization. If the propagation rate constant is 37 L mol -1 s -1 , the termination rate constant is 26 L mol
Consider a chain-growth polymerization. If the propagation rate constant is 37 L mol-1 s-1, the termination rate constant is 26 L mol-1 s-1, the initiator dissociation rate constant is 2 x 10-4 s-1, the initiator efficiency is 0.4, the monomer concentration is 2.3 mol/L, and the initiator concentration is 1.8 millimoles/L, what is the weight average degree of polymerization of the resulting polymer? Assume termination happens via 50% combination and 50% disproportionation. (Note that useful equations for this situation are provided in the textbook 2nd edition, chapter 3, problem 7).
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