Answered step by step
Verified Expert Solution
Link Copied!

Question

1 Approved Answer

Consider a heterogeneous gas-phase catalytic reaction: Catalyst AB (g) A(g) + B (g) The surface reaction mechanism follows three steps: AB (g) + SAB

 

Consider a heterogeneous gas-phase catalytic reaction: Catalyst AB (g) A(g) + B (g) The surface reaction mechanism follows three steps: AB (g) + SAB S (Adsorption) AB SB S+A (g) (Surface reaction) (Desorption) B.SB (g) + S Please derive the rate law assuming each of the three cases: (1) adsorption is rate-limiting, (2) surface reaction is rate limiting, and (3) desorption is rate-limiting. Express the overall reaction rate (AB) in terms of total number of sites on the surface, Ct, partial pressures of the gas species (i.e., PAB, PA and PB), rate constants of adsorption, the surface reaction, and desorption (k, ks, and kn), and the equilibrium constants of adsorption, the surface reaction, and desorption (i.e., KA, KS and KD). Hint: Based on the reaction mechanism, only AB and B are adsorbed on the surface, i.e., there is no evidence that A alone can be adsorbed on the surface.

Step by Step Solution

There are 3 Steps involved in it

Step: 1

blur-text-image

Get Instant Access with AI-Powered Solutions

See step-by-step solutions with expert insights and AI powered tools for academic success

Step: 2

blur-text-image

Step: 3

blur-text-image

Ace Your Homework with AI

Get the answers you need in no time with our AI-driven, step-by-step assistance

Get Started

Recommended Textbook for

Comparative international accounting

Authors: Christopher nobes, Robert parker

9th Edition

273703579, 978-0273703570

Students also viewed these Accounting questions

Question

Distinguish between operating mergers and financial mergers.

Answered: 1 week ago

Question

=+a) Is this an observational or experimental study?

Answered: 1 week ago

Question

Distinguish between a direct and an indirect cost. (pp. 27-28)

Answered: 1 week ago