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Consider a portable 20 cm 2 active area fuel cell operating steadily at 0.75V and 0.6 A/cm 2 The fuel utilization efficiency is 50%, and

Consider a portable 20 cm2 active area fuel cell operating steadily at 0.75V and 0.6 A/cm2

The fuel utilization efficiency is 50%, and cathode stoichiometry is 2.3 expected to run for 3 days. The cathode operates on ambient air, and anode runs off compressed H2.

  1. Determine the volume of the H2 fuel tank required if it is stored as a compressed gas at 200 atm (20. 26 Mpa), 298K.
  2. How large would a pure oxygen container be if it was used to provide the oxidizer? Consider 200 atm (20.26 Mpa) storage pressure and 298 K average ambient temperature?

For Anode,

i. Rate of total H2consumption in 3days =a (iA/nF)

= 2.3 x (0.6 A/cm2) x (20 cm2) x 3daysx 24h/day x 3600s/h/(2e- eq/ mole of H2) x (96485C/eq)

= 32.25 mol H2 consumed = 32.25mol x 2 g/mol = 64.5 g H2 (check the calculation here)

PV = m(RT/MW); V H2 = (mR/MW) x (T/P)

= [(64.5 g) x (8.314 J/mol.K) ]/(2g/mol) x (298K/20,260,000 Pa)= 0.0039 m3

= 3.9 L

ii. Similar to i. ;c = 2.3 & MW O2= 32g/mole




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