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Consider the hydro dealkylation of toluene ( HDA ) process to produce benzene. The desired production rate for benzene is 2 6 5 kmol /

Consider the hydro dealkylation of toluene (HDA) process to produce benzene. The desired production rate for benzene is 265 kmol/h. Toluene feed is pure, but the feed gas contains 95% hydrogen and 5% methane. The following reactions take place.
Toluene + H2-> Benzene + CH4(1)2Benzene Diphenyl + H2(2)
Based on intrinsic kinetics, the selectivity for benzene (S) is related to toluene conversion (x) as S =10.0036. In order to avoid selectivity loss to diphenyl, it is decided to recycle the
(1x)1.544
diphenyl back into the reactor (rather than taking as byproduct). The equilibrium constant for reaction (2) is 0.24. For this design alternative,
(a) Draw the corresponding level 2 and level 3 process flowsheets. Briefly justify elements in these flowsheets.
(b) Consider reactor conversion of 0.75 and mole fraction of hydrogen in purge as 0.4. Also consider that hydrogen to toluene ratio of 5:1(mol to mol) is maintained at the reactor inlet. Perform appropriate material balance and compute level 2 economic potential.
(c) The reactor exit stream is vapor and is cooled to 100 F to obtain vapor-liquid split. Using approximate flash calculations, estimate the value of benzene lost through purge.

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