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Consider the hydro dealkylation of toluene ( HDA ) process to produce benzene. The desired production rate for benzene is 2 6 5 kmol /
Consider the hydro dealkylation of toluene HDA process to produce benzene. The desired production rate for benzene is kmolh Toluene feed is pure, but the feed gas contains hydrogen and methane. The following reactions take place.
Toluene H Benzene CHBenzene Diphenyl H
Based on intrinsic kinetics, the selectivity for benzene S is related to toluene conversion x as S In order to avoid selectivity loss to diphenyl, it is decided to recycle the
x
diphenyl back into the reactor rather than taking as byproduct The equilibrium constant for reaction is For this design alternative,
a Draw the corresponding level and level process flowsheets. Briefly justify elements in these flowsheets.
b Consider reactor conversion of and mole fraction of hydrogen in purge as Also consider that hydrogen to toluene ratio of :mol to mol is maintained at the reactor inlet. Perform appropriate material balance and compute level economic potential.
c The reactor exit stream is vapor and is cooled to F to obtain vaporliquid split. Using approximate flash calculations, estimate the value of benzene lost through purge.
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