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Consider the reversible, isothermal, liquid - phase reaction: A + B 2 C where k 1 is the rate constant for the forward reaction, k

Consider the reversible, isothermal, liquid-phase reaction:
A+B2C
where k1 is the rate constant for the forward reaction, k2 is the rate constant for the backward reaction and Kc=k1k2 is the equilibrium constant. The forward and backward reactions are elementary. The reaction is carried out using equimolar concentrations of species A and B. The equilibrium conversion for this reaction is 80%.
(a) Determine the value of the equilibrium constant Kc and express the rate of disappearance of species A as function of Kc.
[9 marks]
(b) Express the rate of disappearance of species A exclusively as a function of the conversion of species A, the rate constant for the forward reaction k1 and the concentration of species A in the feed stream to the reactor.
[4 marks]
(c) When the same reaction is carried out in a CSTR the conversion of A is measured to be 60%. The equilibrium conversion under the same conditions is known to be 80%. Determine the value of the Damkhler number. Further, determine the conversion of species A if the volumetric flow rate into the CSTR is to be increased by a factor of 1.5 with the inlet concentrations of species A and B and the temperature remaining constant.
[12 marks]
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