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Consider the rovibrational spectrum for the v = 0 v = 1 vibrational transition of H35Cl below, assuming the rotational constant is the same for
Consider the rovibrational spectrum for the v = 0 v = 1 vibrational transition of H35Cl below, assuming the rotational constant is the same for the lowest two vibrational states Bv=0 = Bv=1. (a) List the rotational transitions Ji Jf to which the peaks (i)-(viii) correspond. (b) List the branches to which the peaks the peaks (i)-(vii) belong. (c) Estimate the energy of the pure vibrational (v = 0, J = 0) (v = 1, J = 0) transition in wavenumbers. (d) Approximate the vibrational frequency of the isotopologue H37Cl within the harmonic approximation, assuming the potential remains unchanged. (e) State whether H35Cl or H37Cl is expected to have a larger bond dissociation energy in the Morse approximation
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