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Davies equation: l o g + - = - 0 . 5 1 z + | z - | [ ( I ) 1 2

Davies equation:
log+-=-0.51z+|z-|[(I)121+(I)12-0.30(I)]
where I=12i?zi2(bibo) and b represents molality and z is the charge.
For 3-hydroxypropionic acid, Ka=3.110-5 at 25C.
Estimate the molality of H+in a 0.120m solution of 3-hydroxypropionic acid that also contains
0.100mNaNO3 at 25C. Use the Davies equation to estimate ionic activity coefficients. Neglect
ion pairing.
Estimate the molality of H+in a buffer solution having 0.12m3-hydroxypropionic acid and
0.100m sodium 3-hydroxypropionate at 25C. Use the Davies equation to estimate ionic activity
coefficients. Neglect ion pairing.
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