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Explain or rationalise as many trends and comparisons as you can in the data in the following tabulation of 10Dq values (all in units
Explain or rationalise as many trends and comparisons as you can in the data in the following tabulation of 10Dq values (all in units of cm-; in all cases there are six ligand donor atoms bonded to the central metal ion). LIGANDS urea carbonate oxalate water a ammonia cyanide Till 16400 b VIII 17800 18600 Cr 16000 17500 17400 21600 26700 Mn 16700 Fell 13200 13700 18600 14300 Coll c 10Dq = 26 400 cm for tris-oxalato-rhodate(III). d 10Dq = 34 100, 41000 cm for the hexa-ammines of Rh, Ir. 17300 18000 C 18200 22900 33500 a Cf. preceding question. b 10Dq = 15 300 cm for the methylurea {OC(NHMe)(NH)} analogue. d
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