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Figure 1 shows a ) the experimentally determined I n - S n binary phase diagramFigure 1 shows a ) the experimentally determined I n

Figure 1 shows a) the experimentally determined In-Sn binary phase diagramFigure 1 shows a) the experimentally determined In-Sn binary phase diagram
(NB. the dashed lines represent uncertain equilibria) and b) Gibbs energy -
composition diagram at 50C. Based on the diagrams please answer following
questions:
a) What is the solubility of Tin in tetragonal Indium at room temperature? (1p)
b) If the nominal composition of the SnIn alloy is xSn=0.6 and T=50C, what
phases are in equilibrium, what are their compositions and what are their relative
amounts (fractions)?(3p)
c) Please explain, how the above mentioned equilibrium and {:T=50C) can
be determined from the Gibbs energy - composition diagram (Figure 1b) and show
graphically, what is the chemical potential of Sn in - and - phases and Sn)
in that equilibrium. (2p)
d) Explain the equilibrium (DLiq=Dsolid=) solidification (i.e. the compositions and
amounts/fractions of phases as a function of temperature) from 250C to 25C
when the nominal composition of the alloy is xSn=0.75.(2p)
e) Please discuss, how the solidification of the same alloy (xSn=0.75) could differ,
if microsegregation (DLiq= and Dsolid=0) would occur? (1p)
a)
Figure 1 a) In-Sn binary phase diagram and b) Gibbs energy - composition diagram at
50C.
(NB. the dashed lines represent uncertain equilibria) and b) Gibbs energy -
composition diagram at 50C. Based on the diagrams please answer following
questions:
a) What is the solubility of Tin in tetragonal Indium at room temperature? (1p)
b) If the nominal composition of the SnIn alloy is xSn2=0.6 and T=50C, what
phases are in equilibrium, what are their compositions and what are their relative
amounts (fractions)?(3p)
c) Please explain, how the above mentioned equilibrium and {:T=50C) can
be determined from the Gibbs energy - composition diagram (Figure 1b) and show
graphically, what is the chemical potential of Sn in - and - phases and Sn)
in that equilibrium. (2p
d) Explain the equilibrium (DLiq=Dsolid=) solidification (i.e. the compositions and
amounts/fractions of phases as a function of temperature) from 250C to 25C
when the nominal composition of the alloy is xSn=0.75.(2p)
e) Please discuss, how the solidification of the same alloy ({:xSn=0.75) could differ,
if microsegregation and {:Dsolid=0) would occur? (1p)
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