For each of the following reactions, provide:

the rate function if the reactions can be assumed to be elementary;

the rate constant with respect to the boxed components $(k_i)$ as a function of the overall rate constant $(k).$

a$)CO+N{O}_{3}2NO+C{O}_2$

b$)2N{O}_2$

c$)(C{H}_3{)}_3\frac{C}{O}OC(C{H}_3{)}_{3}harr{C}_2{H}_6+2C{H}_{3}COC{H}_3$

d$)2NO+2N{O}_2$

e$)C{H}_3\frac{C}{O}O{C}_2{H}_5+C_4{H}_9$OHharr

$+C_2{H}_{5}OH$

f$)A+B3C$