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For increasing coverage of CO on Ni{111} the following overlayer structures are observed: 0.33 ML: p(73 x 73) R30 0.50 ML: C(2 x 4) 0.57
For increasing coverage of CO on Ni{111} the following overlayer structures are observed: 0.33 ML: p(73 x 73) R30 0.50 ML: C(2 x 4) 0.57 ML: p(77 V7) R19 (i) Draw the overlayer unit cell (using the graph paper below) and give the matrix notation for each of the above structures. [3 x 2 marks] (ii) How many molecules per unit cell are there in each of the above structures? [3 marks) (iii) Given the fact, that CO has very strongly repulsive 1st neighbour interactions, which is the largest coverage for which all molecules could occupy identical adsorption sites? Justify your answer. [2 marks]
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