Question
For the electrolytes CuSO, and MgCl,, compute the effective diffusion coefficients and diffusion potentials when a 1mM solution and a 0.1 mM solution are
For the electrolytes CuSO, and MgCl,, compute the effective diffusion coefficients and diffusion potentials when a 1mM solution and a 0.1 mM solution are separated by an uncharged membrane at 25C. TABLE 7.4 Diffusion Coefficients of Anions and Cations at 25C Cation Charge, z4 D.x 10 cm2s! Charge, z Anion D_x 10 cm? s1 H* +1 9.312 OH- -1 5.260 Na+ +1 1.334 -1 2.032 K* +1 1.957 NO; 1.902 +1 NH Mg** 1.954 HCO, 1.105 +2 0.7063 HCO, 1.454 ++ Ca++ +2 0.7920 SO, -2 1.065 Cu+ +2 0.72 HSO, -1 1.33 Source: Adapted from Ref. [5]. Used with permission.
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Materials Science and Engineering An Introduction
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