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for the following question: Three gram-moles of benzene and 7 gram-moles of toluene are placed in a closed cylinder equipped with a piston. The cylinder

for the following question: Three gram-moles of benzene and 7 gram-moles of toluene are placed in a closed cylinder equipped with a piston. The cylinder is immersed in a boiling-water bath that maintains the temperature at 100C. The force exerted on the piston can be varied to adjust the cylinder pressure to any desired value. The pressure is initially 1000 mm Hg and is gradually lowered to 600 mm Hg. Use the Pxy diagram of Figure 6.4-1 to convince yourself that the cylinder initially contains only liquid benzene and toluene and to answer the following questions. a) At what pressure does the first vapor bubble form? What is its composition? (b) At what pressure does the last droplet of liquid evaporate? What is its composition? (c) What are the liquid and vapor compositions in equilibrium with each other when the pressure is 750 mm Hg? What is the ratio (moles vapor/mole liquid) at this point? why did we use 798 mm hg, and 690 mm hg, and 750 mm hg for parts a,b,c when they are not mentioned in the question. how did we calculate them?

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