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For the reaction between two atoms B and C in the gas phase, B+CBC with masses m C and m B and radii r C
For the reaction between two atoms B and C in the gas phase, B+CBC with masses mC and mB and radii rC and rB , find the rate constant using TET and collision theory .Data:
It is necessary to arrive theoretically from the equation of the theory of the transition state to that of collisions. No numerical calculation is necessary.
TTS:
Collisions:
Vqtras=(h22mkBT)3/2,qrot=h282IkBT,Zbc=(rb+rc)2[8kBT]1/2VNbVNc k=hkBTqAqBqXeRTE0 k=(rb+rc)2NAV[8RT]1/2eEthr/RTStep by Step Solution
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