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For the series of silver complexes with cyanide, the C-N stretching vibrations are observed as follows. The species containing three or four cyanide ions

 

For the series of silver complexes with cyanide, the C-N stretching vibrations are observed as follows. The species containing three or four cyanide ions are observed only in solutions containing high concentrations of CN-. Species AgCN solid 2170 Ag(CN) Ag(CN) 2135 2105 Explain the differences in position of the C-N stretching bands. Ag(CN) 2092

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