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For which pair of the fuel gases, calorific value ( C . V . ) of one fuel is almost double that of the other

For which pair of the fuel gases, calorific value (C.V.) of one fuel is almost double that of the other on volume basis (i.e., kcal/Nm3) while the C.V. is same on weight basis (i.e., kcal/kg)?
Propane and acetylene
Propane and LPG
Sewage gas and gobar gas
B.F gas and coke oven gas

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