Question
Fusion of MnO2 along with KOH and O2 forms X. Electrolytic oxidation of X yields Y. X undergoes disproportionation reaction in acidic medium to MnO2
Fusion of MnO2 along with KOH and O2 forms X. Electrolytic oxidation of X yields Y. X undergoes disproportionation reaction in acidic medium to MnO2 and Y. The manganese-containing ions present in W and X, respectively, are Y and Z. Correct statement(s) is(are).
(a) Both Y and Z are coloured and have a tetrahedral shape
(b) In an aqueous acidic solution, Y undergoes a disproportionation reaction to give Z and MnO2
(c) Y is diamagnetic in nature while Z is paramagnetic
(d) In both Y and Z, ?-bonding occurs between p-orbitals of oxygen and d-orbitals of manganese
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Chemistry The Central Science
Authors: Theodore Brown, Eugene LeMay, Bruce Bursten, Catherine Murphy, Patrick Woodward
12th edition
321696727, 978-0132175081, 978-0321696724
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