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Hydrodealkylation is a process in which side chain alkyl groups ( like methyl ) are removed from aromatics by reaction with hydrogen. It is an

Hydrodealkylation is a process in which side chain alkyl groups (like methyl) are removed from aromatics by reaction with
hydrogen. It is an important process in refining of crude oil to higher value fuels or into other valuable chemicals. The following
reactions take place in the reactor:
C6H5CH3?toluene+H2C6H6?benzene+CH4
C6H4(CH3)2+H2C6H5CH3+CH4
xylene
toluene
C6H3(CH3)3+H2C6H4(CH3)2+CH4
pseudocumene
xylene
In addition, an unwanted side reaction occurs, in which two benzenes react to form diphenyl:
2C6H6C6H5C6H5+H2
benzene diphenyl
A process stream containing 10mol% benzene (C6H6),20mol% toluene (C6H5CH3),30mol% xylene C6H4(CH3)2, and 40
mol% pseudocumene C6H3(CH3)3 is fed at a rate of 100gmol to a hydrodealkylation plant. This process stream is mixed with
H2 at 5-molar excess H2 before being fed to the reactor. Hydrogen and methane are separated from the remaining compounds
(lumped together as aromatics). The aromatics are analyzed and found to contain 28mol% pseudocumene, 1mol% diphenyl,
19% benzene, and 1% toluene. Calculate the extents of reaction and fractional conversions of all reactants, the methane
production rate, and the mol% methane in the gas stream.
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