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(i) A simultaneous determination for cobalt and nickel can be based on absorption by their respective 8 hydroxyquinolmol complexes. Molar absorption corresponding to their absorption

(i) A simultaneous determination for cobalt and nickel can be based on absorption by    their respective 8 hydroxyquinolmol complexes. Molar absorption corresponding to their                absorption maxima are as follows.

Molar absorptivity ,

365nm

700nm

Co

3529

428.9

Ni

3228

10.2

Calculate the molar concentration of nickel and cobalt in each of the following solutions using the following data.                

Absorbance A (1.00 cm cell)

Solution

365nm

700nm

a

0.426

0.026

b

0.792

0.081
 

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