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I have tried SO HARD to understand what this is asking and I just can't make sense of it. Problem 1.44. At the back of
I have tried SO HARD to understand what this is asking and I just can't make sense of it.
Problem 1.44. At the back of this book is a table of thermodynamic data for selected substances at room temperature. Browse through the Cp values in this table, and check that you can account for most of them (approximately) using the equipartition theorem. Which values seem anomalous? Substance (form) Al (s) Al2SiOs (kyanite) Al2SiOs andalusite) Al2SiOs (sillimanite) Ar (6) C (graphite) C (diamond) CH4 (g) C2H6 (8) C3H8 (g) C2H5OH (1) C6H12O6 (glucose) CO (8) CO2 (g) H2CO3 (aq) HCO3 (aq) Ca2+ (aq) CaCO3 (calcite) CaCO3 (aragonite) CaCl2 (s) Cl2 (8) ci- (aq) Cu (s) Fe (s) AjH (kJ) A,G (kJ) S (J/K) Cp (J/K) V (cm) 0 0 28.33 24.35 9.99 -2594.29 -2443.88 83.81 121.71 44.09 - 2590.27 -2442.66 93.22 122.72 51.53 -2587.76 -2440.99 96.11 124.52 49.90 0 0 154.84 20.79 0 0 5.74 8.53 5.30 1.895 2.900 2.38 6.11 3.42 -74.81 -50.72 186.26 35.31 -84.68 -32.82 229.60 52.63 -103.85 - 23.49 269.91 73.5 -277.69 -174.78 160.7 111.46 58.4 -1268 -910 212 115 -110.53 -137.17 197.67 29.14 -393.51 -394.36 213.74 37.11 -699.65 -623.08 187.4 -691.99 -586.77 91.2 -542.83 -1206.9 -1207.1 -795.8 -553.58 -1128.8 -1127.8 -748.1 -53.1 92.9 88.7 104.6 81.88 81.25 72.59 36.93 34.15 51.6 0 - 167.16 0 - 131.23 223.07 56.5 33.91 -136.4 17.3 0 0 33.150 24.44 7.12 0 0 27.28 25.10 7.11 Substance (form) H2 (8) H (6) H+ (aq) H20 (1) H20 (8) He (8) Hg (1) N2 (8) NH3 (8) Na+ (aq) NaCl (s) NaAlSi308 (albite) NaAlSi2O6 (jadeite) Ne (8) O2 (s) O2 (aq) OH(aq) Pb (s) PbO2 (s) PbSO4 (s) 50- (aq) HSO, (aq) SiO2 (a quartz) HSiO4 (aq) AgH (kJ) AG (kJ) A,G (kJ) S (J/K) S (J/K) Cp (J/K) V (cm) 0 0 130.68 28.82 217.97 203.25 114.71 20.78 0 0 0 0 -285.83 -237.13 69.91 75.29 18.068 -241.82 -228.57 188.83 33.58 0 0 126.15 20.79 0 0 76.02 27.98 14.81 0 0 191.61 29.12 -46.11 -16.45 192.45 35.06 -240.12 -261.91 59.0 46.4 -1.2 -411.15 -384.14 72.13 50.50 27.01 -3935.1 -3711.5 207.40 205.10 100.07 -3030.9 -2852.1 133.5 160.0 60.40 0 0 146.33 20.79 0 0 205.14 29.38 -11.7 16.4 110.9 - 229.99 -157.24 -10.75 -148.5 0 0 64.81 26.44 18.3 -277.4 -217.33 68.6 64.64 -920.0 -813.0 148.5 103.2 -909.27 -887.34 -744.53 -755.91 20.1 131.8 -293 -84 22.69 -910.94 - 1449.36 -856.64 -1307.67 41.84 215.13 44.43 468.98Step by Step Solution
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