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Important Notice: In this exam, some data are directly generated from your student ID . The x , Y , Z codes are the last

Important Notice: In this exam, some data are directly generated from your student ID. The x,Y,Z
codes are the last three digits of your ID, respectively. For example, if this is your student ID:
060100351, the x=3,Y=5,Z=1.
The Cr-Ni binary system at 1xYZ K exhibits a regular solution. For xNi=0.24 composition,
activity value was obtained as aN=036. Using the given information answer the questions:
a) For xNi=0.4x composition calculate the activity and activity coefficient values of both Cr and
Ni.
b) Calculate the mixing free energy, mixing enthalpy and mixing entropy values of the solution
(xNi=0.4x).
c) Empiric equation to calculate equilibrium vapor pressure of pure Chromium is given below.
Calculate the equilibrium partial pressure of Chromium in the Cr-Ni alloy ).
InP(Cr)o=-45590T-1,27lnT+23,93(atm)
d) If temperature was decreased from 1xYZK to 1000K, would you expect higher, lower or the
same activity coefficient value for Cr and Ni? Explain.
e) Describe the ?-function (interatomic bond parameter). Calculate/find the - function for
the solution. Explain/compare the bond strengths for the solution. Is it an endothermic or
exothermic reaction? Does it require energy?
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