Question
In a cell consisting of glass electrode in solution with pH of 7.0 and a calomel electrode, the emf of glass electrode at 298
In a cell consisting of glass electrode in solution with pH of 7.0 and a calomel electrode, the emf of glass electrode at 298 K was 0.062 V. When a solution of unknown pH replaced the standard buffer, the glass electrode potential was 0.145 V with the glass electrode negative. Calculate the unknown pH if during caliberation, the glass electrode was (a) negative, and (b) positive.
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Fundamentals of Analytical Chemistry
Authors: Douglas A. Skoog, Donald M. West, F. James Holler, Stanley R. Crouch
9th edition
495558281, 978-0495558286
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