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In a cell consisting of glass electrode in solution with pH of 7.0 and a calomel electrode, the emf of glass electrode at 298

In a cell consisting of glass electrode in solution with pH of 7.0 and a calomel electrode, the emf of glass electrode at 298 K was 0.062 V. When a solution of unknown pH replaced the standard buffer, the glass electrode potential was 0.145 V with the glass electrode negative. Calculate the unknown pH if during caliberation, the glass electrode was (a) negative, and (b) positive.

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