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In class, we derived the rather remarkable results that if we know the bandstructure E(k) of any crystal, the velocity of an electron in state
In class, we derived the rather remarkable results that if we know the bandstructure E(k) of any crystal, the velocity of an electron in state k is its group velocity vy(k) = %%l with suitable generalization to higher dimensions, and the motion of the states in kspace is given simply by F' = % where F' is the force. In this problem, consider an electron on a ring of length L moving through an extremely weak periodic crystal po- tential of lattice constant a such that the periodicity of the crystal is imprinted on the electron wavefunctions. (a) Show that in the limit of a vanishing crystal potential, the wavefunction of the electron must be of the form (z) = e'\"a)m, where G = %'rn is a reciprocal lattice vector with n = ... 1,0, +1,.... (b) The Bloch wavefunction is of the form 1 (z) = e**u(z) such that u(z + a) = u(x). Show that the electron wavefunction of part (a) is in the Bloch form. Identify u(z) and prove that indeed u(z + a) = u(z). (c) Show that the allowed electron eigenvalues are E(k) = W. Write expressions for several values of G, and sketch the corresponding nearly free electron energy bands for 3%
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