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In the interest of C O 2 capture, the exit gas ( 1 0 0 kmo l h ) from an alcohol fermenter consists of

In the interest of CO2 capture, the exit gas (100kmolh) from an alcohol fermenter consists of an
air-CO2 mixture containing 10mol%CO2 that is to be absorbed in a recycled 5.0-N solution of
triethanolamine, containing 0.03molCO2 per mol of amine solution. Assume that the column operates
isothermally at 25C, and we desire to absorb 78% of the CO2 in the feed gas to the absorber. Assume
that the gas carrier rate is constant through the absorber, and that negligible water and amine are
stripped. VLE data for CO2 at 25C with this amine solution are tabulated below in mole ratio
coordinates.
(a) Convert the equilibrium data to mole fractions and calculate the VLE K-ratio. Would an assumption of
constant K-ratio be a good idea for this system?
(b) Calculate the mole fraction y and mole ratio Y of CO2 in the exiting gas.
(c) Determine the minimum amount of amine solution using a graphical method and the exiting liquid
mole ratio composition x if the minimum solvent was used.
(d) Using 1.2x the minimum solvent rate, determine the exiting liquid composition x and the number of
stages needed.
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